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Analysis of flow field and charge distribution in a gasoline direct-injection (GDI) engine is performed by a modified version of the KIVA code. A particle-based spray model is proposed to simulate a swirl-type hollow-cone spray in a GDI engine. Spray droplets are assumed to be fully atomized and introduced at the sheet breakup locations as determined by experimental correlations and energy conservation. The effects of the fuel injection parameters such as spray cone angle and ambient pressure are examined for different injectors and injection conditions. Results show reasonable agreement with the measurements for penetration, dispersion, global shape, droplet velocity and size distribution by Phase Doppler Particle Anemometry(PDPA) in a constant-volume chamber. The test engine is a 4-stroke 4-valve optically accessible single-cylinder engine with a pent-roof head and tumble ports.

The direct injection spray-wall interactions were investigated experimentally using high-speed laser-sheet imaging, shadowgraphy, wetted footprints and phase Doppler interferometry techniques. A narrow-cone high-pressure swirl injector is used to inject iso-octane fuel onto a plate, at three different impact angles inside a pressurized chamber. Heated air and plate conditions were compared with unheated cases. Injection interval was also varied in the heated case to compare dry- and wet- wall impingement behaviors. High-speed macroscopic Mie-scattering images showed that presence of wall and air temperature has only minor effect on the bulk spray structure and penetration speed for the narrow-cone injector tested. The overall bulk motions of the spray plume and its spatial position at a given time are basically unaffected until a few millimeters before impacting the wall.

A quantitative and time-resolved technique has been developed to probe the fuel distribution very near the nozzle of a high-pressure diesel injector. This technique uses the absorption of synchrotron x-rays to measure the fuel mass with good time and position resolution. The penetrating power of x-rays allows measurements that are difficult with other techniques, such as quantitative measurements of the mass and penetration measurements of the trailing edge of the spray. Line-of-sight measurements were used to determine the fuel density as a function of time. The high time resolution and quantitative nature of the measurement also permit an accurate measure of the instantaneous mass flow rate through the nozzle.

Experimental data is used in conjunction with multi-dimensional modeling in a modified version of the KIVA-3V code to characterize the emissions behavior of a high-speed, direct-injection diesel engine. Injection pressure and EGR are varied across a range of typical small-bore diesel operating conditions and the resulting soot-NOx tradeoff is analyzed. Good agreement is obtained between experimental and modeling trends; the HSDI engine shows increasing soot and decreasing NOx with higher EGR and lower injection pressure. The model also indicates that most of the NOx is formed in the region where the bulk of the initial heat release first takes place, both for zero and high EGR cases. The mechanism of NOx reduction with high EGR is shown to be primarily through a decrease in thermal NOx formation rate.

The emissions trade-off and combustion characteristics of a high speed, small-bore, direct injection, single cylinder, diesel engine are investigated at three different load conditions. The experiments covered a wide range of parameters including the injection pressure, exhaust gas recirculation (EGR) rate and swirl ratio (Sw). The effects of each parameter on the ignition delay (ID), apparent rate of energy release (ARER), NOx, Bosch smoke unit (BSU), CO and hydrocarbons are investigated. The results show that the NOx emission dropped continuously with the increase in EGR (up to 55%), but with increasing smoke emission in a classical trade-off relationship. The increase in injection pressure generally reduced smoke with NOx penalty; however, the NOx penalty decreased at higher EGR. There also appears to be an increase in the cool flame intensity at the high EGR rates. Applying swirl at high EGR rate and high injection pressure conditions further reduced smoke emissions.

A quantitative and time-resolved technique has been developed to probe the dense spray structure of direct-injection (DI) gasoline sprays in near-nozzle region. This technique uses the line-of-sight absorption of monochromatic x-rays from a synchrotron source to measure the fuel mass with time resolution better than 1 μs. The small scattering cross-section of fuel at x-rays regime allows direct measurements of spray structure that are difficult with most visible-light optical techniques. Appropriate models were developed to determine the fuel density as a function of time.

The effects of the start/stop (S/S) transients on the Hybrid Electric Vehicle (HEV) operation and emissions are explored in this study. The frequency with which the engine starts and stops during an urban driving cycle is estimated by using the NREL's Advanced Vehicle Simulator software (ADVISOR). Furthermore, several tests were conducted on single-cylinder and multi-cylinder direct injection diesel engines in order to measure the cycle-resolved mole fractions of the hydrocarbons and nitric oxide exhaust emissions under frequent start/stop mode of operation. The frictional losses in engine in its entirety as well as in its components are also determined. In addition, the dynamic behavior of different high pressure fuel injection systems are investigated under the start and stop mode of operation.

Combustion characteristics of the emulsified diesel fuels are investigated in a Rapid Compression and Expansion Machine(RCEM). Among the test cases the 40 W/O fuel injected at BTDC 20° has shown the best performance with respect to the efficiency and NOx and soot emissions. The pressure trace of the 40 W/O fuel is characterized by a longer ignition delay and a lower rate of pressure rise in premixed combustion. High speed photographs show reduced flame luminosity and lower flame temperature with the increasing W/O ratio. Micro-explosions of emulsified fuel droplets which affect the local shape and brightness of the flame are identified in magnified flame images.

Although improvements in NOx adsorber formulations are increasing the sulfur resistance of these materials, and legislation continues to further restrict sulfur levels in fuels, sulfur poisoning remains as one of the key issues associated with successful commercialization of NOx adsorber technology throughout the world. Because of the stability of the sulfate poisons, high temperatures which stress the thermal stability of some of the most efficient NOx adsorbents are required for desulfation. Additionally, the rich condition which favors sulfur release simultaneously increases the H2S content of the emission. Sulfur traps offer the potential for reducing the formation of poisoning sulfates on downstream NOx adsorbents. Results characterizing the sulfur scavenging efficiency of these materials, as well as the conditions required for their regeneration will be presented. Strategies for their successful application on motor vehicles will be discussed.

High-speed video of combustion processes and cylinder pressure traces were obtained from a single-cylinder optical-accessible engine with a production four-valve cylinder head to study the mixture formation and flame propagation characteristics at near-stoichiometric start condition. Laser-sheet Mie-scattering images were collected for liquid droplet distributions inside the cylinder to correlate the mixture formation process with the combustion results. A dual-stream (DS) injector and a quad-stream (QS) injector were used to study the spray dispersion effect on engine starting, under different injection timings, throttle valve positions, engine speeds, and intake temperatures. It was found that most of the fuel under open-valve injection (OVI) conditions entered the cylinder as droplet mist. A significant part of the fuel droplets hit the far end of the cylinder wall at the exhaust-valve side.

The autoignition delay of a turbulent methane jet in a Diesel-like environment is calculated by the conditional moment closure(CMC) model. Methane is injected into hot air in a constant volume chamber under various temperatures and pressures. Detailed chemical reaction mechanisms are implemented with turbulence-chemistry interaction treated by the first order CMC. The CMC model solves the conditional mean species mass fraction and temperature equations with the source term given in terms of the conditional mean quantities. The flow and mixing field are calculated by the transient SIMPLE algorithm with the k -ε model and the assumed beta function pdf. The CMC equations are solved by the fractional step method which sequentially treats the transport and chemical reaction terms in each time step. The predictions in quiescent homogeneous mixture are presented to evaluate the effects of turbulence in jet ignition.

An experimental study was conducted to characterize the dynamics and spray behavior of a wide range of minisac and Valve-Covered-Orifice (VCO) nozzles using a high-pressure diesel common-rail system. The measurements show that the resultant injection-rate is strongly dependent on common-rail pressure, nozzle hole diameter, and nozzle type. For split injection the dwell between injections strongly affects the second injection in regards to the needle lift profile and the injected fuel amount. The minisac nozzle can be used to achieve shorter pilot injections at lower common-rail pressures than the VCO nozzle. Penetration photographs of spray development in a high pressure, optical spray chamber were obtained and analyzed for each test condition. Spray symmetry and spray structure were found to depend significantly on the nozzle type.

Advances in extrusion die technology allow ceramic substrate suppliers to provide new monolithic automotive substrates with considerably higher cell densities and thinner wall thicknesses. These new substrates offer both faster light off and better steady state efficiencies providing new flexibility in the design of automotive catalytic converters. The effectiveness-NTU methodology is used to evaluate various design parameters of the HCD substrates. Various theoretical derivations are supported with experimental results on substrates with cell densities ranging from 400 to 1200 cells per square inch with varying wall thicknesses. Performance effects such as steady state conversion, transient response both thermal and emission, flow restriction and FTP emissions results are evaluated. Poison deposition is studied and the effects on emissions performance evaluated.

An experimental study was carried out to visualize the spray and combustion inside an AVL single-cylinder research diesel engine converted for optical access. The injection system was a hydraulically-amplified electronically-controlled unit injector capable of high injection pressure up to 180 MPa and injection rate shaping. The injection characteristics were carefully characterized with injection rate meter and with spray visualization in high-pressure chamber. The intake air was supplied by a compressor and heated with a 40kW electrical heater to simulate turbocharged intake condition. In addition to injection and cylinder pressure measurements, the experiment used 16-mm high-speed movie photography to directly visualize the global structures of the sprays and ignition process. The results showed that optically accessible engines provide very useful information for studying the diesel combustion conditions, which also provided a very critical test for diesel combustion models.

The direct injection gasoline spray-wall interaction was characterized inside a heated pressurized chamber using various visualization techniques, including high-speed laser-sheet macroscopic and microscopic movies up to 25,000 frames per second, shadowgraph, and doublespark particle image velocimetry. Two hollow cone high-pressure swirl injectors having different cone angles were used to inject gasoline onto a heated plate at two different impingement angles. Based on the visualization results, the overall transient spray impingement structure, fuel film formation, and preliminary droplet size and velocity were analyzed. The results show that upward spray vortex inside the spray is more obvious at elevated temperature condition, particularly for the wide-cone-angle injector, due to the vaporization of small droplets and decreased air density. Film build-up on the surface is clearly observed at both ambient and elevated temperature, especially for narrow cone spray.

Dual-brick catalyst systems containing Pd-only catalysts followed by Pt/Rh three-way catalysts (TWCs) provide an effective strategy for managing Pt, Pd and Rh precious metal inventories while achieving LEV/ULEV emission standards. Engine aged dual-brick converters containing front Pd catalysts followed by rear Pd/Rh or Pt/Rh TWCs demonstrated LEV emission levels in an underfloor location on a TLEV calibrated 3.8L vehicle, and achieved ULEV emissions with air addition. Using identical advanced washcoat formulations stabilized with ceria-zirconia promoters, single-brick Pt/Rh TWCs demonstrated equivalent performance to Pd/Rh TWCs after thermally severe aging, and dual-brick [Pd + Pt/Rh] systems also had equivalent performance to [Pd + Pd/Rh] catalyst systems. While a Pd-only system also achieved 100K mi equivalent LEV emissions, both dual-brick options lowered emissions further using substantially lower loadings and more balanced precious metal usage.

This paper presents a computer model for simulating dynamic responses inside an injector of an automotive fuel rail system. The injector contains a filter at the top, a coil spring in the middle, and a needle and orifices at the bottom. The equations of motion for unsteady one-dimensional flow are derived for the fluid flowing through the injector. The needle motion is described by a second order ordinary differential equation. The forces exerted on the needle include the magnetic force that controls the opening and closing of the injector and the coil spring force. To account for the loss of kinetic energy, we define two loss factors Ka and Kb. The former describes the loss of kinetic energy as fluid enters the injector through the filter at the top, and the latter depicts that as fluid is ejected into a large chamber through the passage between the needle and the needle seat and across four orifices at the bottom of the injector.

A computer model is developed for predicting pressure fluctuations inside an automotive electronic fuel rail system, which consists of six injectors connected in series through pipelines and a pressure regulator. The pressure fluctuations are mainly caused by opening and closing of injectors fired in a particular order. The needles that control the opening and closing of the injectors are modeled by mass- spring-dashpot systems, whose equations of motion are governed by a second order ordinary differential equations. A similar second order ordinary differential equation is used to describe the motion of the membrane with nonlinear stiffness inside the pressure regulator. The responses of injectors and pressure regulator are coupled by unsteady one-dimensional flow through the pipelines. The pressure fluctuations are also required to satisfy a one-dimensional damped wave equation. To validate this computer model, pressure fluctuations inside injectors and pipelines are calculated.

The understanding of deactivation mechanisms is critical to the development of NOx adsorber catalysts with improved durability. The thermal deactivation of a state-of-the-art Pt/Rh based NOx adsorber catalyst is evaluated following oven agings at 800 and 900°C. Sulfur poisoning during lean/rich cycling is studied as a function of catalyst inlet temperature and SO2 concentration. Complementing these studies utilizing synthetic exhaust gas compositions, deactivation resulting from three different engine aging schedules is examined. The performance of engine-aged catalysts is evaluated as received, and following desulfurization procedures differing in inlet temperature and air/fuel ratio. The impact of aging schedules on NOx adsorption and three-way catalyst function is discussed with respect to precious metal dispersion, washcoat sintering, as well as sulfur build-up and oil-derived poisonings.

An experimental study was carried out to characterize the exhaust flow structure inside the closed-coupled catalytic converter, which is installed on a firing four-cylinder 12-valve passenger car gasoline engine. Simultaneous velocity and pressure measurements were taken using cycle-resolved Laser Doppler anemometer (LDA) technique and pressure transducer. A small fraction of titanium (IV) iso-propoxide was dissolved in gasoline to generate titanium dioxide during combustion as seeding particles for the LDA measurements. It was found that the velocity is highly fluctuating due to the pulsating nature of the engine exhaust flow, which strongly depends on the engine operating conditions and the measuring locations. The pressure oscillation is correlated with the transient exhaust flow characteristics. The main exhaust flow event from each cylinder can only be observed at the certain region in front of the monolith brick.